The parliament has been split, as have most state institutions, since soon after it was elected in 2014, as Libya broke between warring factions in the east and west.
Regional experts say Palestinians will continue to suffer from the Israeli occupation despite the change of guard in the government.
Warring parties have agreed on delaying the formation of a power-sharing government by six months.
The fall of Sirte, a main DAESH stronghold in Libya, would be a major defeat for the terror group as it has also lost ground in Syria and Iraq.
Libya's UN-backed unity government will begin taking control of three ministries in attempt to assert itself ahead of vote
First clashes erupt in Tripoli since UN-backed government's arrival after French and German foreign ministers fly to Libya to support unity government
Tripoli government withdraws support for Libya's new UN-backed unity government just one day after making promise to cede power
Libya's UN-backed unity government gets major boost after Tripoli administration cedes power
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